Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration.
نویسندگان
چکیده
A novel radical phosphinylation of α,α-diaryl allylic alcohols with arylphosphine oxides was described for the direct preparation of α-aryl-β-phosphinylated carbonyl ketones in medium to good yields via 1,2-aryl migration. In this reaction, formation of new C(Ar)-C(sp(3)) and C(sp(3))-P bonds was observed.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 57 شماره
صفحات -
تاریخ انتشار 2014